Concepedia

The Role of Metal Hydroxide Complexes in Late Transition Metal‐Mediated Transmetalation Reaction: The Case of Gold

Stéphanie Dupuy, L. Ellis Crawford, Alexandra M. Z. Slawin, Steven P. Nolan

Advanced Synthesis & Catalysis · 2012 · 42 citations · 28 references

DOI

Concepts

Abstract

Abstract In gold chemistry, the hydroxide function on the metal center was observed to act as a potent transmetalation group facilitator when reacted with boronic acids leading to the exceedingly rapid formation of gold‐aryl bonds.

References

28

The Development and Catalytic Uses of N-Heterocyclic Carbene Gold Complexes

Steven P. Nolan · Accounts of Chemical Research · 2010 · 645 citations · Full text

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Synthesis and Structural Characterization of <i>N</i>-Heterocyclic Carbene Gold(I) Complexes

Pierre de Frémont, Natalie Scott, Edwin D. Stevens et al. · Organometallics · 2005 · 487 citations

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Tandem Au-Catalyzed 3,3-Rearrangement−[2 + 2] Cycloadditions of Propargylic Esters:  Expeditious Access to Highly Functionalized 2,3-Indoline-Fused Cyclobutanes

Liming Zhang · Journal of the American Chemical Society · 2005 · 454 citations

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Distinguishing Between Pathways for Transmetalation in Suzuki−Miyaura Reactions

Brad P. Carrow, John F. Hartwig · Journal of the American Chemical Society · 2011 · 453 citations · Full text

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Kinetic Data for the Transmetalation/Reductive Elimination in Palladium‐Catalyzed Suzuki–Miyaura Reactions: Unexpected Triple Role of Hydroxide Ions Used as Base

Christian Amatore, Anny Jutand, Gaëtan Le Duc · Chemistry - A European Journal · 2011 · 368 citations

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