Concepedia

Gold-Catalyzed Tandem 1,3-Migration/[2 + 2] Cycloaddition of 1,7-Enyne Benzoates to Azabicyclo[4.2.0]oct-5-enes

Weidong Rao, Dewi Susanti, Philip Wai Hong Chan

Journal of the American Chemical Society · 2011 · 123 citations · 45 references

Concepts

EngineeringHeterocyclicAlkene MetathesisGold-catalyzed Tandem 1,3-Migration/Organic ChemistrySynthetic MethodCatalysisChemistryHeterocycle Chemistry1,7-Enyne BenzoatesEnantioselective SynthesisBiomolecular Engineering

Abstract

A synthetic method that relies on gold(I)-catalyzed tandem 1,3-migration/[2 + 2] cycloaddition of 1,7-enyne benzoates to prepare azabicyclo[4.2.0]oct-5-enes is described.

References

45

Gold Catalysis

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Inorganic Chemistry, Chemical Engineering, Engineering +9

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A. Stephen K. Hashmi · Angewandte Chemie International Edition · 2010 · 1.1K citations

Biochemistry, Natural Sciences, Heterogeneous Catalysis +9

Gold and Platinum Catalysis of Enyne Cycloisomerization

Liming Zhang, Jianwei Sun, Sergey A. Kozmin · Advanced Synthesis & Catalysis · 2006 · 885 citations

Engineering, Heterocyclic, Platinum Catalysis +11

Molecular diversity through gold catalysis with alkynes

Eloísa Jiménez‐Núñez, Antonio M. Echavarren · Chemical Communications · 2006 · 803 citations

Cross-coupling Reaction, Novel Organocatalysts, Engineering +14

Tandem Au-Catalyzed 3,3-Rearrangement−[2 + 2] Cycloadditions of Propargylic Esters: Expeditious Access to Highly Functionalized 2,3-Indoline-Fused Cyclobutanes

Liming Zhang · Journal of the American Chemical Society · 2005 · 450 citations