Concepedia

Homogeneous catalysis: use of chiral titanocene complexes for asymmetric catalytic Diels–Alder reactions

William Odenkirk, B. Bosnich

Journal of the Chemical Society Chemical Communications · 1995 · 30 citations · 18 references

DOI

Concepts

Abstract

A stable, chiral diaquo titanocene complex is an excellent catalyst for certain Diels–Alder reactions giving good enantioselectivity which indicates that catalysis occurs by metal rather than by proton activation of the dienophile.

References

18

Designed catalyst for enantioselective Diels-Alder addition from a C2-symmetric chiral bis(oxazoline)-iron(III) complex

E. J. Corey, Nobuyuki Imai, Hong Yue Zhang · Journal of the American Chemical Society · 1991 · 442 citations

, , +15

Bis(oxazoline)copper(II) complexes as chiral catalysts for the enantioselective Diels-Alder reaction

David A. Evans, Scott J. Miller, Thomas Lectka · Journal of the American Chemical Society · 1993 · 270 citations

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Catalysis of Diels-Alder reactions by low oxidation state transition-metal Lewis acids: fact and fiction

Peter V. Bonnesen, Craig L. Puckett, Robert V. Honeychuck et al. · Journal of the American Chemical Society · 1989 · 143 citations

, , +13

Asymmetric Diels–Alder reaction catalysed by chiral alkoxyaluminium dichloride

Shunichi Hashimoto, N Komeshima, Kenji Koga · Journal of the Chemical Society Chemical Communications · 1979 · 142 citations

, , +6

Asymmetric hetero Diels-Alder reactions catalyzed by novel chiral vanadium(IV) bis(1,3-diketonato) complexes

Antonio Togni · Organometallics · 1990 · 117 citations

, , +7