A Novel Pillar-Layered Organic−Inorganic Hybrid Based on Lanthanide Polymer and Polyomolybdate Clusters: New Opportunity toward the Design and Synthesis of Porous Framework

Abstract

An unprecedented microporous lanthanum polymolybdate, [{La(H2O)5(dipic)}{La(H2O)(dipic)}]2{Mo8O26}·10H2O (H2dipic = pyridine-2,6-dicarboxylic acid) 1, which is constructed from lanthanum−organic coordination polymer sheets pillared by individual octamolybdate clusters, is reported.