Concepedia

Novel MoFeS Clusters from [(C<sub>5</sub>Me<sub>5</sub>)<sub>2</sub>Mo<sub>2</sub>S<sub>4</sub>] and Fe(CO)<sub>5</sub> or Fe<sub>2</sub>(CO)<sub>9</sub>

Henri Brunner, Norbert Janietz, Joachim Wächter, Thomas Zahn, Manfred L. Ziegler

Angewandte Chemie International Edition in English · 1985 · 34 citations · 7 references

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Abstract

The synthesis of novel tri- and tetranuclear clusters in the MoFeS system can be accomplished by addition of Fe(CO)5 or Fe2(CO)9 to the complex [(C5Me5)2Mo2S4]. An example is 1, a 62e-“heterocubane”. It contains five MM bonds (not shown); the FeFe distance (no bonding) is 3.334 Å.

References

7

Investigation into the reactivity of the metal-metal triple bond in [Cp'(CO)2M]2 (Cp' = .eta.5-C5Me5', M = Mo, W) vs. elemental sulfur. Formation of different Cp'2M2S4 isomers and crystal structures of Cp'2Mo2(.mu.-S2)(.mu.-S)2 and Cp'2(CO)2W2(.mu.-S)2S

Henri Brunner, Walter Meier, Joachim Wächter et al. · Organometallics · 1982 · 92 citations

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Facile synthesis of Cp2Mo2(.mu.-SH)2(.mu.-S)2 and its use in heterobimetallic cluster synthesis

Peter Williams · Inorganic Chemistry · 1983 · 59 citations

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Stepwise assembly of heterometallic M4S4 clusters. The structure of bis[(methylcyclopentadienyl)vanadium] bis(nitrosyliron) sulfide [(MeCp)2V2Fe2(NO)2S4], a 58e cubane

Thomas B. Rauchfuss, Timothy D. Weatherill, Scott R. Wilson et al. · Journal of the American Chemical Society · 1983 · 48 citations

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Synthesis of organovanadium sulfide cluster compounds via bis(methylcyclopentadienyl)divanadium tetrasulfide

C. Mark Bolinger, Thomas B. Rauchfuss, Scott R. Wilson · Journal of the American Chemical Society · 1982 · 38 citations

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A General Method for the Synthesis of Heterometal Clusters of the M<sub>2</sub>Fe<sub>2</sub>S<sub>4</sub>‐Cubane Type (M Cr, Mo)

Henri Brunner, Heike Kauermann, Joachim Wächter · Angewandte Chemie International Edition in English · 1983 · 25 citations · Full text

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