Macromolecular Materials and Engineering · 2011 · 30 citations · 22 references
EngineeringMaterials EngineeringMaterials ScienceHeat TransferPolymer EngineeringPolymer MaterialsHeat ConductionHeat Transfer FundamentalsHeat Transfer In SolidsThermal Properties Of MaterialsThermal SensorsThermosetsElectrical Resistance MeasurementReaction ProgressThermal ConductivityThermal Conductivity MeasurementsThermal TransferThermally Conductive PolymersVulcanizationVulcanization Kinetics
Abstract The thermal conductivity of a rubber compound is studied as a function of its state of curing. The device is presented and the calculations in order to obtain samples with controlled and homogeneous vulcanization rates are performed. The hot disk technique is used to measure the thermal conductivity of the rubber. This transient, plane‐source and non‐destructive method allows rapid and accurate measurement of the thermal conductivity based on the measurement of the electrical resistance of a plane sensor placed between two identical samples. The obtained results show that the thermal conductivity may vary significantly as a function of vulcanization rate. The effect of this variation on the prediction of the reaction progress is discussed. magnified image
22
Statistical mechanics of chain molecules
Paul J. Flory, M.V. Volkenstein · Biopolymers · 1969 · 6.5K citations
Natural Sciences, Chemistry, Physics +14
<i>The Physics of Rubber Elasticity</i>
L. R. G. Treloar, D. J. Montgomery · Physics Today · 1959 · 3.8K citations
Natural Sciences, Materials Engineering, Materials Science +17
The physics of rubber elasticity
B Zimm, R.W. Kilb · Journal of Physics and Chemistry of Solids · 1959 · 3K citations