Poly(Vinyl Pyridine) as a Universal Surface Modifier for Immobilization of Nanoparticles

Abstract

Metal, metal oxide, and plastic surfaces were modified with poly(vinylpyridine) using adsorption, spin-coating, and dip-coating techniques and various metal, semiconductor, and dielectric nanoparticles were subsequently attached. Prior to the modification, the substrates were treated with glow discharge plasma for cleaning purposes and to introduce surface functional groups that are capable of interaction with the polymer. UV−vis absorption spectroscopy, atomic force, and electron scanning microscopies were used to characterize polymer layers and layers of immobilized nanoparticles. The surface modification with poly(vinylpyridine) via adsorption technique is suggested as a simple, effective, and highly versatile method for the preparation of single, mixed, and multilayered assemblies of various nanoparticles on different substrates.