Synthesis and Spectroscopic Characterization of Heteroleptic Europium(III) Double-deckers Containing 2,3-Naphthalocyaninato and Tetra(4-pyridyl)porphyrinato Ligands

Jianzhuang Jiang, Da‐Ming Du, Michael T. M. Choi, Jinglei Xie, Dennis K. P. Ng

Chemistry Letters · 1999 · 30 citations · 16 references

Concepts

Abstract

Abstract The first heteroleptic 2,3-naphthalocyaninato and porphyrinato double-decker complexes, namely Eu(Nc)(TPyP) (1) and Eu[Nc’(SC12H25)8](TPyP) (2), were prepared by the base-promoted cyclization of 2,3-dicyanonaphthalenes using Eu(TPyP)(acac) as the template, and were spectroscopically characterized.

References

16