Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals/Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals · 1996 · 18 citations · 1 references
Natural SciencesChemistryMaterials ScienceElectroanalytical MethodsElectrochemical EngineeringElectrochemistryElectrochemical SynthesisElectrode MaterialsRedox-active MaterialsConductivityElectronic Conductivity
Several derivatives of higher homologues of bis-fused TTF, BDT-TTPY (1) and DT-TTP (2), have been synthesized. Cyclic voltammograms of 1 and 2consist of three-pairs of double-electron and five-pairs of single electron redox waves, respectively. Most of cation radical salts obtained by the chemical doping with appropriate oxidants showed relatively high conductivity ([sgrave]rt =10-2-101 S cm1 on compressed pellets).
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