Publication | Closed Access
Organometallic Chemistry of [W<sub>2</sub>(OCH<sub>2</sub><i>t</i>Bu)<sub>8</sub>]
21
Citations
11
References
1997
Year
Materials ScienceInorganic ChemistryUnusual OrientationEngineeringCoordination ComplexSeveral Tungsten ComplexesBridging Ethyne LigandMolecular ComplexChemistryInorganic SynthesisInorganic Compound
An unusual orientation of the bond is shown by the bridging ethyne ligand in complex 1, which is prepared from [W2(OCH2tBu)8] and ethyne: the crystal structure analysis of 1 revealed that the CC bond of this ligand is neither parallel nor perpendicular to the WW bond, but at an angle of 67° to it. Furthermore, the reactivity studies of [W2(OCH2tBu)8] with CO, ethene, allene, benzophenone, and thiobenzophenone have provided several tungsten complexes with remarkable structures.
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