Photochemically Reversible Liquefaction and Solidification of Single Compounds Based on a Sugar Alcohol Scaffold with Multi Azo‐Arms

Abstract

Sugar alcohol derivatives with multi azobenzene arms are photochemically and isothermally liquefied from a powdered solid upon irradiation with ultraviolet light at room temperature, and then solidified on irradiation with visible light, where the transition between solid and liquid are reversible. These compounds possess similar chemical structures to comb-like liquid crystalline oligomers.