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CARBON-13 NUCLEAR MAGNETIC RESONANCE OF METAL COMPLEXES. I.
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Citations
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References
1973
Year
Inorganic ChemistryBiochemistryChemical Shift ValuesNatural SciencesCoordination ComplexMagnetic ResonanceCyanometallate ComplexesMolecular ComplexFourier-transform Nmr SpectroscopyChemistrySpectra-structure Correlation
Abstract Carbon-13 chemical shifts were measured for 15 cyanometallate complexes in aqueous solution with Fourier-Transform NMR spectroscopy. The chemical shift values are distributed between −50.33 ppm (from external benzene standard) for Fe(CN)64− and +2.66 ppm for Pt(CN)42−. The coupling constant 1JC-Co was found to be 126 ± 4 Hz for Co(CN)63−.
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