Science · 2006 · 242 citations · 25 references
Natural SciencesChemistryEarth SciencesAtmospheric ChemistryGeochemistryPlanetary GeologyCloud MicrophysicsGrain-surface ChemistryIce ChemistryIce MicrophysicsMolecular CloudsProtoplanetary Disk ChemistryAtmospheric Chemical ReactionsFractionationIsotopic AnalysisIsotopic FractionationMeteorite IsotopesOrganic CoatingsOrganic Matter Refractory FractionRefractory Organic Carbon
Coordinated transmission electron microscopy and isotopic measurements of organic globules in the Tagish Lake meteorite shows that they have elevated ratios of nitrogen-15 to nitrogen-14 (1.2 to 2 times terrestrial) and of deuterium to hydrogen (2.5 to 9 times terrestrial). These isotopic anomalies are indicative of mass fractionation during chemical reactions at extremely low temperatures (10 to 20 kelvin), characteristic of cold molecular clouds and the outer protosolar disk. The globules probably originated as organic ice coatings on preexisting grains that were photochemically processed into refractory organic matter. The globules resemble cometary carbon, hydrogen, oxygen, and nitrogen (CHON) particles, suggesting that such grains were important constituents of the solar system starting materials.
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Meteorites and the Early Solar System
Edward Anders · Annual Review of Astronomy and Astrophysics · 1971 · 1.6K citations · Full text
Natural Sciences, Astronomy, Physics +11
Interstellar Ice: The <i>Infrared Space Observatory</i> Legacy
E. L. Gibb, D. C. B. Whittet, A. C. A. Boogert et al. · The Astrophysical Journal Supplement Series · 2004 · 829 citations · Full text
Deuterium fractionation in dense interstellar clouds
T. J. Millar, Alec Bennett, Eric Herbst · The Astrophysical Journal · 1989 · 413 citations
Interstellar Chemistry Recorded in Organic Matter from Primitive Meteorites
H. Busemann, Andrea F. Young, C. M. O'd. Alexander et al. · Science · 2006 · 364 citations