Concepedia

Giant Organometallic Networks Derived from Ferrocenepolysulfides

Collin P. Galloway, Thomas B. Rauchfuss

Angewandte Chemie International Edition in English · 1993 · 57 citations · 13 references

DOI

Concepts

Abstract

Desulfurization with tributylphosphane converts the ferrocenepolysulfide 1 into three-dimensional network polymers. These consist of ferrocene subunits interconnected by oligosulfide crosslinks. Gel permeation chromatography on an analogous polymerized alkyl derivative of 1 indicates molecular weights in excess of 106 Da. •=Fe.

References

13

Ring-opening polymerization of strained, ring-tilted ferrocenophanes: a route to high-molecular-weight poly(ferrocenylsilanes)

Daniel A. Foucher, Ben Zhong Tang, Ian Manners · Journal of the American Chemical Society · 1992 · 596 citations

, , +9

Symmetrically disubstituted ferrocenes

J. J. BISHOP, Alan Davison, Murray L. Katcher et al. · Journal of Organometallic Chemistry · 1971 · 394 citations

Arborols Based on Luminescent and Redox‐Active Transition Metal Complexes

Scolastica Serroni, Gianfranco Denti, Sebastiano Campagna et al. · Angewandte Chemie International Edition in English · 1992 · 191 citations

, , +14

o-Lithiothiophenol equivalents. Generation, reactions and applications in synthesis of hindered thiolate ligands

Eric Block, Venkatachalam Eswarakrishnan, Michael Gernon et al. · Journal of the American Chemical Society · 1989 · 155 citations

, , +5

Polyferrocenylene persulfides

Paul F. Brandt, Thomas B. Rauchfuss · Journal of the American Chemical Society · 1992 · 148 citations

, , +5