Publication | Closed Access
Supramolecular stabilization of hydroxylamine TEMPOH by complexation with an amphiphilic calixarene
13
Citations
22
References
2005
Year
Supramolecular StabilizationEngineeringSupramolecular AssemblyBiochemistryNatural SciencesRadical (Chemistry)Stable Inclusion ComplexOrganic ChemistryAmphiphilic SystemChemistryAmphiphilic CalixarenePhenolic Oh GroupEthanol/water MixtureBiomolecular EngineeringHydroxylamine Tempoh
In an ethanol/water mixture, the nitroxyl radical TEMPO abstracts a hydrogen atom from a phenolic OH group of the amphiphilic para-hexanoylcalix[4]arene, and the hydroxylamine TEMPOH formed yields a stable inclusion complex with another molecule of the calixarene.
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