Concepedia

C–F bond activation by iridium(<scp>I</scp>). A unique process involving P–C bond cleavage, P–F bond formation and net retention of oxidation state

Ofer Blum, Felix Frolow, David Milstein

Journal of the Chemical Society Chemical Communications · 1991 · 90 citations · 17 references

DOI

Concepts

Abstract

Reaction of hexafluorobenzene with MeIr(PEt3)3 results in a unique process involving C–F bond cleavage, P–C bond cleavage and P–F bond formation, yielding the crystallographically characterized iridium (I) complex 2.

References

17

Organometallic thermochemistry. Metal hydrocarbyl, hydride, halide, carbonyl, amide, and alkoxide bond enthalpy relationships and their implications in pentamethylcyclopentadienyl and cyclopentadienyl complexes of zirconium and hafnium

Laurel E. Schock, Tobin J. Marks · Journal of the American Chemical Society · 1988 · 269 citations

, , +16

Oxidative additions of aryl, vinyl, and acyl halides to triethylphosphinenickel(0) complexes

Darryl R. Fahey, John E. Mahan · Journal of the American Chemical Society · 1977 · 179 citations

, , +9

Formation, structures, and reactivity of cis-hydroxy-, cis-methoxy-, and cis-mercaptoiridium hydrides. Oxidative addition of water to Ir(I)

David Milstein, Joseph C. Calabrese, Ian D. Williams · Journal of the American Chemical Society · 1986 · 127 citations

, , +6

Oxidative addition of aryl–halogen bonds to platinum(<scp>II</scp>) and the structure of a complex formed by aryl–fluoride oxidative addition

Craig M. Anderson, Richard J. Puddephatt, George Ferguson et al. · Journal of the Chemical Society Chemical Communications · 1989 · 77 citations

, , +9

Activation of carbon-fluorine bonds by oxidative addition

Thomas G. Richmond, Carolyn E. Osterberg, Atta M. Arif · Journal of the American Chemical Society · 1987 · 75 citations

, , +8