Chemical Communications · 2012 · 182 citations · 46 references
Natural SciencesChemistryMaterials ScienceComputational ChemistryMaterials ChemistrySolid-state ChemistryCarbon Dioxide RemovalInorganic MaterialsAdsorption-based CaptureCarbon Capture MaterialsFirst-principles ModelingMesoporous AdsorptionMesoporous Hybrid MaterialsMetal-organic Framework AdsorptionMetal-organic FrameworksSelectivity
Two mesoporous and flexible acylamide-functionalized rht-type MOFs exhibit not only high excess unsaturation CO(2) uptake (157 wt%) at 20 bar and 273 K, but also good selectivity of CO(2)/CH(4) (8.6) and CO(2)/N(2) (34.3). The advantages of acylamide groups for CO(2) capture have been further confirmed by GCMC and first-principles calculations.
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Reticular synthesis and the design of new materials
Omar M. Yaghi, M. O’Keeffe, N.W. Ockwig et al. · Nature · 2003 · 9K citations
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