Fe₂O₃-Pillared Rectorite as an Efficient and Stable Fenton-Like Heterogeneous Catalyst for Photodegradation of Organic Contaminants

Abstract

An efficient Fe(2)O(3)-pillared rectorite (Fe-R) clay was successfully developed as a heterogeneous catalyst for photo-Fenton degradation of organic contaminants. X-ray diffraction analysis and high-resolution transmission electron microscope analysis clearly showed the existence of the Fe(2)O(3) nanoparticles in the Fe-R catalyst. The catalytic activity of the Fe-R catalyst was evaluated by the discoloration and chemical oxygen demand (COD) removal of an azo-dye rhodamine B (RhB, 100 mg/L) and a typical persistent organic pollutant 4-nitrophenol (4-NP, 50 mg/L) in the presence of hydrogen peroxide (H(2)O(2)) under visible light irradiation (lambda > 420 nm). It was found that the discoloration rate of the two contaminants was over 99.3%, and the COD removal rate of the two contaminants was over 87.0%. The Fe-R catalyst showed strong adsorbability for the RhB in the aqueous solution. Moreover, the Fe-R catalyst still showed good stability for the degradation of RhB after five recycles. Zeta potential and Fourier transform infrared spectroscopy were used to examine the photoreaction processes. Finally, a possible photocatalytic mechanism was proposed.