Cyclic Voltammetry for Electron Transfer Reactions at Liquid/Liquid Interfaces

Abstract

Abstract A theory for cyclic voltammetry at liquid/liquid interfaces for electron transfer is proposed, and the numerical solution of the resulting integral equation is evaluated. This theory has been used to show how the cyclic voltammograms, for electron transfer at ITIES, vary when different ratios of reactants and products, in both phases, are used, and how these voltammograms differ from classical cyclic voltammograms.