Concepedia

STUDIES ON ORGANOPHOSPHORUS COMPOUNDS 102. A CONVENIENT STEREOSPECIFIC SYNTHESIS OF DIALKYL 1-ALKYL(ARYL)-2-NITROETH-1-ENYLPHOSPHONATES

Qun Yuan, Peng He, Chengye Yuan

Phosphorus, sulfur, and silicon and the related elements · 1997 · 14 citations · 3 references

DOI

Concepts

Abstract

Abstract Dialkyl 1-alkyl(aryl)-2-nitroeth-1-enylphosphonates were prepared by treatment of dialkyl 1-alkyl(aryl)-1-hydroxyl-2-nitroalkylphosphonates with thionyl chloride and pyridine. The dehydration process underwent stereospecifically providing exclusively the E-isomers. An E2 reaction mechanism was suggested.

References

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Claude Benezra · Journal of the American Chemical Society · 1973 · 100 citations

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The Reactions of Aroyl Halides with Phosphites. Esters of Aroylphosphonic Acids

K. Darrell Berlin, H. A. Taylor · Journal of the American Chemical Society · 1964 · 96 citations

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STUDIES ON ORGANOPHOSPHORUS COMPOUNDS 95. A NOVEL SYNTHESIS OF 2-TRIFLUOROMETHYL-2-(SUBSTITUTED AMINO)ETHYLPHOSPHONATES

Wei-Sheng Huang, Chengye Yuan · Phosphorus, sulfur, and silicon and the related elements · 1995 · 10 citations

, , +4