Sensors · 2012 · 454 citations · 120 references
Natural SciencesMaterials EngineeringMaterials ScienceNanomaterialsNanotechnologyThin FilmsChemical SensorsGas SensorsNanostructured Electronic MaterialsOxide SemiconductorsSemiconductor NanomaterialsSemiconductor Thin FilmsGas SensingGrain Size ReductionNanostructured Gas SensorsNanostructured OxidesNanostructured SensorsNanostructuresSemiconductor Gas SensorsSemiconductor Oxide Thin Films
Recently, the hydrogen gas sensing properties of semiconductor oxide (SMO) nanostructures have been widely investigated. In this article, we provide a comprehensive review of the research progress in the last five years concerning hydrogen gas sensors based on SMO thin film and one-dimensional (1D) nanostructures. The hydrogen sensing mechanism of SMO nanostructures and some critical issues are discussed. Doping, noble metal-decoration, heterojunctions and size reduction have been investigated and proved to be effective methods for improving the sensing performance of SMO thin films and 1D nanostructures. The effect on the hydrogen response of SMO thin films and 1D nanostructures of grain boundary and crystal orientation, as well as the sensor architecture, including electrode size and nanojunctions have also been studied. Finally, we also discuss some challenges for the future applications of SMO nanostructured hydrogen sensors.
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