Publication | Closed Access
Gold(I)-Catalyzed Asymmetric Cyclopropenation of Internal Alkynes
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Citations
55
References
2012
Year
Chemical EngineeringEnantioselective SynthesisEngineeringAlkene MetathesisInternal AlkynesSilver HexafluoroantimonateOrganic ChemistryOrganometallic CatalysisCatalysisChemistryAsymmetric CatalysisBinuclear Gold Catalyst
Highly enantioselective cyclopropenation of internal alkynes with aryldiazoacetates was achieved using the binuclear gold catalyst (S)-xylylBINAP(AuCl)(2), activated by silver hexafluoroantimonate.
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