Nucleophile-directed selectivity towards linear carbonates in the niobium pentaethoxide-catalysed cycloaddition of CO<sub>2</sub> and propylene oxide

Barnali Dutta, Julien Sofack‐Kreutzer, Amylia A. Ghani, Valerio D’Elia, Jérémie D. A. Pelletier, Mirza Cokoja, Fritz E. Kühn, Jean‐Marie Basset

Catalysis Science & Technology · 2014 · 58 citations · 35 references

Concepts

Abstract

The reaction between CO<sub>2</sub> and propylene oxide in the presence of Nb(EtO)<sub>5</sub> and 4-dimethylaminopyridine leads to the formation of an acyclic carbonate through an unprecedented pathway.

References

35