Nucleophilic participation in the solvolysis of the -butyldimethylsulfonium ion

The Correlation of Solvolysis Rates

Ernest Grunwald, S. Winstein · Journal of the American Chemical Society · 1948 · 695 citations

Natural Sciences, Chemistry, Analytical Chemistry +5

The SN2-SN1 spectrum. 2. Quantitative treatments of nucleophilic solvent assistance. A scale of solvent nucleophilicities

Frank L. Schadt, T. William Bentley, Paul von Ragué Schleyer · Journal of the American Chemical Society · 1976 · 344 citations

Natural Sciences, Chemistry, Analytical Chemistry +4

Linear solvation energy relationships. 15. Heterolytic decomposition of the tert-butyl halides

Michael H. Abraham, R. W. TAFT, Mortimer J. Kamlet · The Journal of Organic Chemistry · 1981 · 64 citations

Natural Sciences, Chemistry, Inorganic Chemistry +6

Solvolysis rates and deuterium isotope effects in 2,2,2-trifluoroethanol-water mixtures

V. J. Shiner, William Dowd, Robert D. Fisher et al. · Journal of the American Chemical Society · 1969 · 64 citations

Natural Sciences, Chemistry, Analytical Chemistry +12

SN2 character of solvolyses of tert-butyl halides and of trifluoroacetolyses of secondary alkyl sulfonates

T. William Bentley, Christine T. Bowen, W. Parker et al. · Journal of the American Chemical Society · 1979 · 52 citations

Natural Sciences, Chemistry, Inorganic Chemistry +5