Concepedia

Palladium-catalyzed Reaction of Olefins and Acetylenes with Iodoferrocenes

Akira Kasahara, Taeko Izumi, Mitsugi Maemura

Bulletin of the Chemical Society of Japan · 1977 · 23 citations · 7 references

DOI

Concepts

Abstract

Abstract Iodoferrocene (1) reacts readily with olefinic compounds in the presence of a catalytic amount of palladium(II) acetate to produce alkenylferrocene derivatives. In the presence of a copper(I) iodide and palladium complex, 1 also reacts with acetylene to afford diferrocenylacetylene.

References

7

Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides

Richard F. Heck, J. P. Nolley · The Journal of Organic Chemistry · 1972 · 2.2K citations

, , +11

Organophosphinepalladium complexes as catalysts for vinylic hydrogen substitution reactions

Harold A. Dieck, Richard F. Heck · Journal of the American Chemical Society · 1974 · 402 citations

, , +6

Palladium-catalyzed arylation of allylic alcohols with aryl halides

John B. Melpolder, Richard F. Heck · The Journal of Organic Chemistry · 1976 · 262 citations

, , +11

A Convenient Synthesis of Some Haloferrocenes

Richard W. Fish, Myron Rosenblum · The Journal of Organic Chemistry · 1965 · 130 citations

, , +4

Palladium-catalyzed vinyl substitution reactions. I. New synthesis of 2- and 3-phenyl-substituted allylic alcohols, aldehydes, and ketones from allylic alcohols

Alan J. Chalk, S. A. Magennis · The Journal of Organic Chemistry · 1976 · 129 citations

, , +7