Concepedia

A one-dimensional germanium sulfide polymer akin to the ionosilicates: synthesis and structural characterization of DPA-GS-8, Ge4S9(C3H7)2NH2(C3H7)NH2(C2H5)

David M. Nellis, Younghee Ko, Kemin Tan, Stephen A. Koch, John B. Parise

Journal of the Chemical Society Chemical Communications · 1995 · 19 citations · 2 references

Concepts

Materials ScienceInorganic ChemistryStructural CharacterizationInorganic CompoundEngineeringNatural SciencesMolecular BiologyStructure ElucidationCorner-linked Adamantane UnitsMain Group ChemistryChemistryChain-like StructureInorganic MaterialFunctional MaterialsInorganic SynthesisLinear Chain Compound

Abstract

Ge4S9(C3H7)2NH2(C3H7)NH2(C2H5) consists of chains of corner-linked adamantane units with a composition of [Ge4S9]2– which are separated by two dipropylammonium (DPA) cations; the first reported chain-like structure of [Ge4S9]2–.

References

2

Directed Transformation of Molecules to Solids: Synthesis of a Microporous Sulfide from Molecular Germanium Sulfide Cages

Omar M. Yaghi, Zhe Sun, David A. Richardson et al. · Journal of the American Chemical Society · 1994 · 293 citations

Engineering, Chemical Transformation, Chemical Analysis +16

Thio‐ and Seleno‐Compounds of Main Group Elements—Novel Inorganic Oligomers and Polymers

Bernt Krebs · Angewandte Chemie International Edition in English · 1983 · 260 citations

Materials Science, Inorganic Chemistry, Chemical Engineering +11