Concepedia

Intramolecular iron(ii)-catalyzed aminobromination of allyl N-tosyloxycarbamates

Takuma Kamon, Daisuke Shigeoka, Tetsuaki Tanaka, Takehiko Yoshimitsu

Organic & Biomolecular Chemistry · 2012 · 19 citations · 27 references

DOI

Concepts

Abstract

Allyl N-tosyloxycarbamates are found to be catalytically transformed into β-brominated oxazolidinones with FeBr(2)/n-Bu(4)NBr in t-BuOH.

References

27

Fenton's reagent revisited

Cheves Walling · Accounts of Chemical Research · 1975 · 2.8K citations

, , +6

<i>N-</i>Tosyloxycarbamates as a Source of Metal Nitrenes:  Rhodium-Catalyzed C−H Insertion and Aziridination Reactions

H. Lebel, Kim Huard, Sylvain Lectard · Journal of the American Chemical Society · 2005 · 314 citations

, , +9

Oxidative Diamination of Alkenes with Ureas as Nitrogen Sources:  Mechanistic Pathways in the Presence of a High Oxidation State Palladium Catalyst

Kilian Muñiz, Claas H. Hövelmann, Jan Streuff · Journal of the American Chemical Society · 2007 · 288 citations

, , +14

Recent Development of Regio‐ and Stereoselective Aminohalogenation Reaction of Alkenes

Guigen Li, S. R. S. Saibabu Kotti, Cody Timmons · European Journal of Organic Chemistry · 2007 · 188 citations

, , +4

<i>N</i>‐Tosyloxycarbamates as Reagents in Rhodium‐Catalyzed CH Amination Reactions

Kim Huard, H. Lebel · Chemistry - A European Journal · 2008 · 178 citations

, , +11