Faraday Discussions of the Chemical Society · 1973 · 84 citations · 0 references
Natural SciencesChemistryPhysicsAtomic PhysicsMolecular PhysicsPhysical ChemistryAtomistic ModelingHydrogen AtomInteratomic PotentialsMolecular ScatteringScattering TheoryAtomic ScatteringIntegral Cross SectionInteratomic Potential ModelsLennard-jones PotentialMolecular Potential ModelsMolecular Scattering TheoryVelocity
Integral elastic cross sections of hydrogen atoms scattered by rare gases have been measured in the velocity range 1.4–14 × 105 cm s–1(0.01 < Ecm < 1.00 eV). The experimental data have been fitted to the Lennard-Jones and exp (α,6) potential models and are found to provide information on the attractive and repulsive parts of the potential. The potential well parameters ε, Rm and the Born-Mayer repulsive potential parameters A, α have been determined for all of the rare gases. These ε, Rm parameters, in combination with the corresponding rare gas dimer parameters, are shown to be consistent with combining rules.