Concepedia

Benzenehexathiol as a template rim for a golden wheel: synthesis and structure of [{CSAu(PPh3)}6]

Annette Schier, J. RIEDE, Hubert Schmidbaur

Journal of the Chemical Society Dalton Transactions · 1994 · 47 citations · 7 references

DOI

Concepts

Abstract

The reaction of benzenehexathiol, C6(SH)6, with [Au(PPh3)Cl] in the presence of triethylamine gave the hexanuclear gold(I) compound [{CSAu(PPh3)}6] whose structure has been determined; the hexagon of the central benzene carbon atoms is surrounded by a hexagon of sulfur atoms, followed by a hexagon of gold atoms and the wheel-like structure is completed by six peripheral phosphine ligands with interlocked aryl groups.

References

7

Synthesis of water-soluble undecagold cluster compounds of potential importance in electron microscopic and other studies of biological systems

Paul A. Bartlett, Barr Bauer, S. J. Singer · Journal of the American Chemical Society · 1978 · 169 citations

, , +8

Synthesis and characterization of gold(I) thiolates, selenolates, and tellurolates: x-ray crystal structures of Au4[TeC(SiMe3)3]4, Au4[SC(SiMe3)3]4, and Ph3PAu[TeC(SiMe3)3]

Philip J. Bonasia, David E. Gindelberger, John Arnold · Inorganic Chemistry · 1993 · 119 citations

, , +6

Synthesis and characterization of dinuclear gold(I) ring and open-ring complexes containing saturated and unsaturated dithiol bridging ligands and phosphine or bis(diphosphine) donor ligands. Crystal structures of [Au2(.mu.-S(CH2)3S) (.mu.-dppm)], [Au2(.mu.-MNT)(PPh3)2], [Au2(.mu.-S2C6H4) (PPh3)2], and [Au4(.mu.-S2C6H3CH3)2(PEt3)2]

Rosa M. Dávila, Anabel Elduque, Tiffany A. Grant et al. · Inorganic Chemistry · 1993 · 103 citations

, , +8

Preparation and Crystal Structures of Gold(I) Complexes of a Series of Benzenethiolates: Pair Formation by Gold‐to‐Gold Interactions of (Benzenethiolato)(triphenylphosphane)gold(I)

Masami Nakamoto, Wolfgang Hiller, Hubert Schmidbaur · Chemische Berichte · 1993 · 65 citations

, , +13

Oxidation of the phosphine from the auranofin analog, triisopropylphosphine(2,3,4,6-tetra-O-acetyl-1-thio-.beta.-D-glucopyranosato-S)gold(I), via a protein-bound phosphonium intermediate

C. Frank Shaw, Anvarhusein A. Isab, James D. Hoeschele et al. · Journal of the American Chemical Society · 1994 · 42 citations

, , +7