Neptunium(vi) chain and neptunium(vi/v) mixed valence cluster complexes

S.M. Cornet, L.J.L. Haller, Mark J. Sarsfield, David Collison, Madeleine Helliwell, Iain May, Nikolas Kaltsoyannis

Chemical Communications · 2009 · 51 citations · 31 references

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Abstract

The synthesis of [Np(VI)O(2)Cl(2)(thf)](n) offers the potential for more detailed exploration of neptunyl(vi) chemistry, while the synthesis of the mixed valence cluster complex [{Np(VI)O(2)Cl(2)}{Np(V)O(2)Cl(thf)(3)}(2)] allows molecular neptunyl(v) 'cation-cation' interactions to be probed.

References

31