Concepedia

Structure and Characterization of the First Metal Complex of Dithiaporphyrin:  Ru(S<sub>2</sub>TTP)Cl<sub>2</sub>

Chen‐Hsiung Hung, Chen-Kuo Ou, Gene‐Hsiang Lee, Shie‐Ming Peng

Inorganic Chemistry · 2001 · 34 citations · 16 references

DOI

Concepts

Abstract

The ruthenium complex of tetratolyldithiaporphyrin was synthesized and characterized. The solid-state structure demonstrates that, in order to accommodate ruthenium metal in the central core, the thiophene rings tilt away from the dithiaporphyrin core and coordinate to metal in an η1-pyrimidal side-on fashion.

References

16

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