A cis-influence of π-bonding ligands in two rhodium() complexes

Peter B. Hitchcock, Mary McPartlin, R. MASON

Journal of the Chemical Society D Chemical Communications · 1969 · 47 citations · 0 references

Concepts

Abstract

The molecular geometries of tris(triphenylphosphine)rhodium(I) chloride and bistriphenylphosphine(tetrafluoroethylene)rhodium(I) chloride illustrate a cis-influence of perfluoroethylene relative to triphenylphosphine.