Physical review. A, General physics · 1983 · 672 citations · 41 references
Discrete GeometryRandom Close PackingEngineeringPhysicsSimple DefinitionProbability TheoryStochastic GeometryDiscrete MathematicsVoronoi DiagramCombinatorial OptimizationHard Spheres
The paper defines random close packing of hard spheres and investigates its implications. Random close packing is defined as the minimum packing fraction where the median nearest‑neighbor distance equals the sphere diameter, and the authors estimate this fraction by extrapolating radial distribution function data from dilute concentrations. The estimated critical packing fractions are 0.64 ± 0.02 in three dimensions and 0.82 ± 0.02 in two dimensions, matching experimental observations.
A simple definition of random close packing of hard spheres is presented, and the consequences of this definition are explored. According to this definition, random close packing occurs at the minimum packing fraction $\ensuremath{\eta}$ for which the median nearest-neighbor radius equals the diameter of the spheres. Using the radial distribution function at more dilute concentrations to estimate median nearest-neighbor radii, lower bounds on the critical packing fraction ${\ensuremath{\eta}}_{\mathrm{RCP}}$ are obtained and the value of ${\ensuremath{\eta}}_{\mathrm{RCP}}$ is estimated by extrapolation. Random close packing is predicted to occur for ${\ensuremath{\eta}}_{\mathrm{RCP}}=0.64\ifmmode\pm\else\textpm\fi{}0.02$ in three dimensions and ${\ensuremath{\eta}}_{\mathrm{RCP}}=0.82\ifmmode\pm\else\textpm\fi{}0.02$ in two dimensions. Both of these predictions are shown to be consistent with the available experimental data.
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Stochastic Problems in Physics and Astronomy
S. Chandrasekhar · Reviews of Modern Physics · 1943 · 8.4K citations
Equation of State for Nonattracting Rigid Spheres
Norman F. Carnahan, K.E. Starling · The Journal of Chemical Physics · 1969 · 5.2K citations
Engineering, Physics, Mechanics +8