Concepedia

Ruthenium porphyrin encapsulated in modified mesoporous molecular sieve MCM-41 for alkene oxidation

Chunjing Liu, Shou‐Gui Li, Wenqin Pang, Chi‐Ming Che

Chemical Communications · 1997 · 203 citations · 3 references

Concepts

EngineeringOrganic ChemistryNanoheterogeneous CatalysisChemistryChemical EngineeringOrganometallic CatalysisMaterials ScienceInorganic ChemistryAlkene OxidationMolecular SieveStable CatalystCatalysisRuthenium PorphyrinHydrogenCatalytic SynthesisHeterogeneous CatalysisCatalyst PreparationTert-butyl HydroperoxideDeoxygenation

Abstract

Ruthenium(II) meso-tetrakis(4-chlorophenyl)porphyrinencapsulated in MCM-41 modified with 3-aminopropyltriethoxysilane is a stable catalyst for alkene oxidation by tert-butyl hydroperoxide with high product turnovers.

References

3

Zeolite-encapsulated and clay-intercalated metal porphyrin, phthalocyanine and Schiff-base complexes as models for biomimetic oxidation catalysts: an overview

Fethi Bédioui · Coordination Chemistry Reviews · 1995 · 431 citations

Inorganic Chemistry, Clay-intercalated Metal Porphyrin, Chemical Engineering +9

Redox properties of metalloporphyrin excited states, lifetimes, and related properties of a series of para-substituted tetraphenylporphine carbonyl complexes of ruthenium(II)

D. Paul Rillema, Jeffrey K. Nagle, L. F. Barringer et al. · Journal of the American Chemical Society · 1981 · 157 citations

Inorganic Chemistry, Chemical Engineering, Engineering +12

Synthesis and Catalytic Capability of Zeolite-Encapsulated Iron and Manganese Tetramethylporphine Complexes

Nakamura Makoto, Takashi Tatsumi, Hiro-o Tominaga · Bulletin of the Chemical Society of Japan · 1990 · 86 citations · Full text

Materials Science, Inorganic Chemistry, Chemical Engineering +14