Asymmetric Diels–Alder reaction: comparison of menthoxyaluminium and lanthanide chiral catalysts

Miguel Quimpère, Krzysztof Jankowski

Journal of the Chemical Society Chemical Communications · 1987 · 55 citations · 0 references

Concepts

Abstract

Some dihydropyran carboxylates synthesized via the Diels–Alder reaction with chiral catalysts display an enantiomeric excess of up to 16% for menthoxyaluminium and up to 64% for chiral lanthanide catalysts.