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Asymmetric Heck-type Hydroarylation of Norbornene with Phenyl Triflate Catalyzed by Palladium Complexes of Chiral (β-<i>N</i>-Sulfonylaminoalkyl)phosphines<sup>1</sup>
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1994
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Cross-coupling ReactionPhenyl Triflate CatalyzedDerivativesEngineeringPalladium ComplexesOrganic ChemistryPhosphine DerivativesOrganometallic CatalysisCatalysisAsymmetric Heck-type HydroarylationChemistryAsymmetric CatalysisEnantioselective SynthesisBiomolecular Engineering
It was found that the palladium complexes of chiral (ß-aminoalkyl)phosphine derivatives bearing N-sulfonyl groups were efficient catalysts for asymmetric Heck-type hydroarylation of norbomene with phenyl triflate.