Dirhodium Tetracarboxylates Derived from Adamantylglycine as Chiral Catalysts for Enantioselective C−H Aminations

Ravisekhara P. Reddy, Huw M. L. Davies

Organic Letters · 2006 · 266 citations · 55 references

Concepts

Abstract

The dirhodium tetracarboxylate, Rh(2)(S-TCPTAD)(4), derived from adamantylglycine, is an effective chiral catalyst for both inter- and intramolecular C-H aminations. [reaction: see text]

References

55