Ionic and Organometallic Reductions with N‐Heterocyclic Carbene Boranes

Qianli Chu, Malika Makhlouf Brahmi, Andrey Solovyev, Shau‐Hua Ueng, Dennis P. Curran, Max Malacrìa, Louis Fensterbank, Emmanuel Lacôte

Chemistry - A European Journal · 2009 · 92 citations · 19 references

Concepts

Abstract

Surgical reduction: N-Heterocyclic carbene–borane complexes such as depicted are neutral, organic soluble analogues of borohydride anions with a weak hydridic character, compatible with organometallic catalysis. They are applicable for surgical reductions in complex, multifunctional molecules.

References

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