Accounts of Chemical Research · 1989 · 103 citations · 33 references
Natural SciencesMaterials SciencePhysicsCondensed Matter PhysicsInorganic ChemistrySolid State PhysicsHigh-temperature MaterialsStrongly Correlated Electron SystemsSuperconducting MaterialsCuprate SuperconductorsHigh-temperature SuperconductivityHigh-temperature SuperconductorsResearch ArticlesSuperconducting Critical Temperature
High-temperature superconductivity constitutes the \nmost sensational discovery of recent times. Since these \nnew superconductors are complex metal oxides, chemistry \nhas had a big role to play in the investigations. For \nthe first time, stoichiometry, structure, bonding, and \nsuch chemical factors have formed central themes in \nsuperconductivity, an area traditionally dominated by \nphysicists. These oxide superconductors have given a \nbig boost to solid-state chemistry.
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Bulk superconductivity at 120 K in the Tl–Ca/Ba–Cu–O system
Z. Z. Sheng, A. M. Hermann · Nature · 1988 · 1.1K citations
Crystal structure of the high-temperature superconductor TI2Ba2CaCu2O8
M.A. Subramanian, J. C. CALABRESE, C.C. Torardi et al. · Nature · 1988 · 431 citations