Technometrics · 1974 · 146 citations · 8 references
Natural SciencesChemical EngineeringChemistryAnalytical ChemistryChemical KineticsChromatographic AnalysisAnalytical ChromatographyChemical Reaction KineticsCurve FittingCurve ModelingInstrumental AnalysisReaction Mechanism AnalysisChemical Equilibrium ConstantsChemical MeasurementChemical Reaction MechanismsChemometric AnalysisEquilibrium ConstantsNonlinear RegressionNonlinear Regression ModelsReaction Rate Constant Estimation
The paper presents a method for resolving additive mixtures of overlapping curves by combining nonlinear regression and principal component analysis. The method can be applied to spectroscopy, chromatography, etc. The method makes use of the postulated chemical reaction, and allows one to check the reaction and estimate chemical rate and equilibrium constants.
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Self Modeling Curve Resolution
William H. Lawton, E. A. Sylvestre · Technometrics · 1971 · 883 citations
Elimination of Linear Parameters in Nonlinear Regression
William H. Lawton, E. A. Sylvestre · Technometrics · 1971 · 142 citations