Concepedia

Palladium-Catalyzed Oxidative Alkynylation of Alkenes via C−C Bond Cleavage under Oxygen Atmosphere

Takahiro Nishimura, Hitoshi Araki, Yasunari Maeda, Sakae Uemura

Organic Letters · 2003 · 138 citations · 17 references

DOI

Concepts

Abstract

Palladium-catalyzed oxidative alkynylation of alkenes using tert-propargylic alcohols as alkynylation reagents via C-C bond cleavage under an oxygen atmosphere affords the corresponding ene-yne compounds.

References

17

Palladium(II)-Catalyzed Oxidation of Alcohols to Aldehydes and Ketones by Molecular Oxygen

Takahiro Nishimura, Tomoaki Onoue, Kouichi Ohe et al. · The Journal of Organic Chemistry · 1999 · 466 citations

, , +16

Pd(OAc)2-catalyzed oxidation of alcohols to aldehydes and ketones by molecular oxygen

Takahiro Nishimura, Tomoaki Onoue, Kouichi Ohe et al. · Tetrahedron Letters · 1998 · 214 citations

, , +13

Palladium-Catalyzed Arylative Carbon−Carbon Bond Cleavage of α,α-Disubstituted Arylmethanols

Yoshito Terao, Hiroyuki Wakui, Tetsuya Satoh et al. · Journal of the American Chemical Society · 2001 · 212 citations

, , +9

Palladium(II)-Catalyzed Oxidative Ring Cleavage of <i>tert</i>-Cyclobutanols under Oxygen Atmosphere

Takahiro Nishimura, Kouichi Ohe, Sakae Uemura · Journal of the American Chemical Society · 1999 · 204 citations

, , +7

Ligand-Modulated Palladium Oxidation Catalysis:  Mechanistic Insights into Aerobic Alcohol Oxidation with the Pd(OAc)<sub>2</sub>/Pyridine Catalyst System

Bradley A. Steinhoff, Shannon S. Stahl · Organic Letters · 2002 · 198 citations

, , +17