Concepedia

Enantioselective isotactic alternating copolymerization of styrene and 4‐methylstyrene with carbon monoxide catalyzed by a cationic bioxazoline pd(II) complex

Stefano Bartolini, Carla Carfagna, A. Musco

Macromolecular Rapid Communications · 1995 · 112 citations · 12 references

DOI

Concepts

Abstract

Abstract The cationic bioxazoline Pd(II) complex 2 catalyzes the alternating copolymerization of carbon monoxide with styrene and 4‐methylstyrene, respectively, to yield a highly isotactic optically active polymer at room temperature and low carbon monoxide pressure (1–4 atm).

References

12

Chiral semicorrins and related nitrogen heterocycles as ligands in asymmetric catalysis

Andreas Pfaltz · Accounts of Chemical Research · 1993 · 634 citations

, , +8

Mechanistic aspects of metal-catalyzed alternating copolymerization of olefins with carbon monoxide

Ayusman Sen · Accounts of Chemical Research · 1993 · 399 citations

, , +12

Palladium(II) catalysts for living alternating copolymerization of olefins and carbon monoxide

Maurice Brookhart, Francis C. Rix, Joseph M. DeSimone et al. · Journal of the American Chemical Society · 1992 · 292 citations

, , +12

Polymers with Main-Chain Chirality. Synthesis of Highly Isotactic, Optically Active Poly(4-tert-butylstyrene-alt-CO) Using Pd(II) Catalysts Based on C2-Symmetric Bisoxazoline Ligands

Maurice Brookhart, Mark Wagner, G.G.A. Balavoine et al. · Journal of the American Chemical Society · 1994 · 255 citations

, , +11

Rigid bidentate nitrogen ligands in organometallic chemistry and homogeneous catalysis. 3. Insertion of carbon monoxide and alkenes into palladium-carbon bonds of complexes containing rigid bidentate nitrogen ligands: the first example of isolated complexes in stepwise successive insertion reactions on the way to polyketones

Rob van Asselt, Esther E. C. G. Gielens, Richard E. Rülke et al. · Journal of the American Chemical Society · 1994 · 217 citations · Full text

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