Advanced Materials · 2010 · 196 citations · 26 references
Natural SciencesChemical EngineeringChemistryElectrochemistryNanomaterialsSurface ChemistryCatalyst StabilityElectrode MaterialsNanocatalysisNanostructured SurfacesRedox-active MaterialsSurface CatalysisCatalytic NanoparticlesElectrocatalyst DesignElectrocatalystsElectrocatalytic NanomaterialsElectrocatalytic Surface ReactionsIn Situ SpectroscopyNanostructured Electrode MaterialsSurface Reaction Pathways
A robust new electrocatalyst with ultralow Pt loading, great poisoning resistance, and high stability (see figure) shows an over 100-fold increase in the efficiency of formic acid electro-oxidation, compared with the commercial Pt/C catalyst. In situ IR spectroscopy proves that the greatly enhanced performance is mainly achieved by changing reaction pathways using Au clusters, which simultaneously improve the stability. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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