The Journal of Chemical Physics · 1996 · 39 citations · 13 references
EngineeringChemical EngineeringDynamical SystemsProcess DynamicsReaction EngineeringBifurcation TheoryNonlinear DynamicsNonlinear Process DynamicsProcess Time DelayReaction DynamicsTime Delay EffectsBifurcationBifurcation Analysis In Control SystemsDynamic Transient BehaviorHopf BifurcationHopf Bifurcation With DelayNonlinear Dynamical System ResponseParameter ControlSystem Response Analysis
When the control parameter of a dynamical system varies continuously, bifurcation is delayed due to the inertia in the system’s response. We study experimentally the time delay of the supercritical Hopf bifurcation that arises from the parametric drift of the oscillating Belousov–Zhabotinsky reaction under batch conditions. The time-dependent oscillation amplitude and period are analyzed using the normal form of the supercritical Hopf bifurcation with a time-dependent control parameter. We show that this approach describes the time evolution of the entire oscillatory domain from high amplitude to vanishing oscillations.
13