Publication | Open Access
Regioselective oxidative fragmentation of drimanic terpene alcohols: a short, easy and efficient access to natural and synthetic 11-nordrimane terpene derivatives
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2003
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Chemical EngineeringEngineeringJones ReagentHeterocyclicAlkene MetathesisRegioselective Oxidative FragmentationOrganic ChemistryDeoxygenationChemistryEfficient AccessSelective CrDrimanic Terpene Alcohols11-Nordrimane SkeletonsSynthetic ChemistryBiomolecular EngineeringNatural Product Synthesis
Using selective Cr(VI) oxidations with Jones reagent and PCC, a regioselective and direct access to different oxygenated 11-nordrimane skeletons was achieved, in good overall yield, starting from naturally occurring drimane terpenes.