Chemistry of Materials · 2006 · 522 citations · 61 references
Natural SciencesMaterials EngineeringMaterials ScienceNanomaterialsNanotechnologyPolymer ChemistryCarbon NanomaterialsCarbon NanotubesColloidal DispersionsNanocompositesNanoparticle DispersionsNanotubesCarbon Nanotube NanocompositesColloidal ProcessingColloidal SuspensionsConductive NanocompositesConductivityNanocomposite ProcessingNanocomposite SynthesisNanomaterial Incorporation
Direct mixing of carbon nanotubes with polymer is the simplest concept for creating conductive nanocomposites. The study describes and illustrates the three main strategies for dispersing carbon nanotubes into a polymer matrix to produce conductive nanocomposites. They modify the polymer or nanotube walls, or generate a stable colloidal system of surfactant‑stabilized nanotubes in water with polymer latex, then remove water to produce a powder that can be processed into the desired shape. Adding a third component yields the most promising results, providing low percolation thresholds and relatively high conductivity levels in an environmentally benign process.
The three main strategies for dispersing carbon nanotubes (NTs) into a polymer matrix to get conductive nanocomposites are described, and illustrated with some appealing examples. The direct mixing of the NTs and the polymer is the 'simplest' concept to achieve this goal. Other approaches concern the modification of either the polymer matrix or the NT walls in order to improve the wetting of the filler with the matrix material, and thus promote the incorporation of the NTs into the polymer matrix. Most promising results seem to be obtained upon the addition of a third component. The basic concept is the generation of a stable colloidal system containing both a suspension of NTs stabilized by surfactant molecules in water, and polymer latex. After removal of the water, the resulting powder can be processed into the desired shape. This versatile and environmentally benign concept offers low percolation thresholds and relatively high conductivity levels.
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