Concepedia

Remarkable Effect of Bases on Core–Shell AgNP@CeO2 Nanocomposite-catalyzed Highly Chemoselective Reduction of Unsaturated Aldehydes

Takato Mitsudome, Motoshi Matoba, Masaaki Yamamoto, Tomoo Mizugaki, Koichiro Jitsukawa, Kiyotomi Kaneda

Chemistry Letters · 2013 · 14 citations · 36 references

DOI

Concepts

Abstract

Abstract A highly dispersed core–shell silver nanoparticle–ceria nanocomposite catalyst (AgNP@CeO2-D) was prepared. The addition of bases was found to enhance the catalytic efficiency of AgNP@CeO2-D significantly in the chemoselective reduction of diverse unsaturated aldehydes to the corresponding unsaturated alcohols.

References

36

Asymmetric Catalysis by Architectural and Functional Molecular Engineering: Practical Chemo- and Stereoselective Hydrogenation of Ketones

Ryōji Noyori, Takeshi Ohkuma · Angewandte Chemie International Edition · 2001 · 1.9K citations · Full text

, , +15

Lanthanides in organic chemistry. 1. Selective 1,2 reductions of conjugated ketones

Jean Louis Luche · Journal of the American Chemical Society · 1978 · 1.2K citations

, , +7

Lanthanoids in organic synthesis. 6. Reduction of .alpha.-enones by sodium borohydride in the presence of lanthanoid chlorides: synthetic and mechanistic aspects

André Luís Gemal, Jean Louis Luche · Journal of the American Chemical Society · 1981 · 1K citations

, , +5

Selective Hydrogenation of α,β-Unsaturated Aldehydes

P. Gallezot, D. Richard · Catalysis Reviews · 1998 · 967 citations

, , +9

Chemoselective hydrogenation of carbonyl compounds over heterogeneous catalysts

Päivi Mäki‐Arvela, Jakub Hájek, Tapio Salmi et al. · Applied Catalysis A General · 2005 · 634 citations

, , +16