Chemical Communications · 2011 · 11 citations · 19 references
Natural SciencesChemistryMaterials SciencePhysical ChemistrySurface ChemistrySurface ScienceIon ExchangeSurface PhysicsSurface ReactionsSurface ReactivityAnion ExchangeAqueous Surface ReactionsCarbonate Surface ChemistryGold DepositionGold Surface FunctionalizationIonic Liquids
A simple anion metathesis in diluted aqueous carbonate at room temperature affords 1-(12-mercaptododecyl)-3-methyl-imidazolium carbonate (MDMI-HCO(3)) from MDMI salts self-assembled on gold films and nanoparticles. The properties of MDMI-SAM differ from MDMI in solution, for which the anion exchange reaction does not proceed.
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Hung A. Duong, Thomas N. Tekavec, Atta M. Arif et al. · Chemical Communications · 2003 · 310 citations