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Modelling the photosynthetic water oxidation centre: synthesis, structure, and magnetic properties of [Mn<sub>4</sub>O<sub>2</sub>(OAc)<sub>7</sub>(biphy)<sub>2</sub>ClO<sub>4</sub>]·3H<sub>2</sub>O (bipy = 2,2′-bipyridine)
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1987
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Materials ScienceInorganic ChemistryChemical EngineeringMagnetic PropertiesBest Available ModelEngineeringInorganic PhotochemistryPhotosystemsMechanistic PhotochemistryInorganic CompoundPhotocatalysisChemistryPhotosynthesisInorganic SynthesisHealth Sciences
The synthesis, structure, and magnetic properties of [Mn4O2(OAc)7(bipy)2](ClO4)·3H2O, bipy = 2,2′-bipyridine) are reported; this complex is the first tetranuclear oxide-bridged manganese(III) species and represents the best available model for the photosynthetic water oxidation centre.