Concepedia

Alkene Coupling through Triflic Acid Elimination on Platinum(II)

Endre Szuromi, Paul R. Sharp

Organometallics · 2005 · 23 citations · 11 references

DOI

Concepts

Abstract

The Pt(II) complexes (1,5-COD)Pt(OTf)2 and [(COD)Pt(THF)(OTf)]OTf react readily with alkenes (ethylene, cyclopentene, norbornenes) to give coupling products via HOTf elimination. With propylene a simple allyl complex is obtained.

References

11

Catalytic C−H/Olefin Coupling

Fumitoshi Kakiuchi, Shinji Murai · Accounts of Chemical Research · 2002 · 1.1K citations

, , +10

Carbon-hydrogen insertion and .pi.-complex formation reactions of (.eta.5-C5Me5)(PMe3)Ir with ethylene: an intra- and intermolecular isotope effect study

Page O. Stoutland, Robert G. Bergman · Journal of the American Chemical Society · 1988 · 121 citations

, , +13

Pt−Ag Catalyst System for Hydroarylations with Unactivated Arenes and Olefins

D. Karshtedt, Alexis T. Bell, T. Don Tilley · Organometallics · 2004 · 105 citations

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Formation of Hydrido–η<sup>3</sup>‐Allyl Complexes of Ir<sup>III</sup> by Sequential Olefinic CH Bond Activation and CC Coupling of Alkenyl and Olefin Ligands

Ysaías J. Alvarado, Olivier Boutry, Enrique Gutiérrez‐Puebla et al. · Chemistry - A European Journal · 1997 · 101 citations

Coordinated Olefins as Incipient Carbocations:  Catalytic Codimerization of Ethylene and Internal Olefins by a Dicationic Pt(II)−Ethylene Complex

Christine Hahn, Maria Elena Cucciolito, Aldo Vitagliano · Journal of the American Chemical Society · 2002 · 90 citations

, , +14